Bethe-Peierls approximation for linear monodisperse polymers re-examined.

نویسندگان

  • F F Semeriyanov
  • G Heinrich
چکیده

Bethe-Peierls approximation, as it applies to the thermodynamics of polymer melts, is reviewed. We compare the computed configurational entropy of monodisperse linear polymer melt with Monte Carlo data available in the literature. An estimation of the configurational contribution to the total liquid's C(p) is presented. We also discuss the relation between the Kauzmann paradox and polymer semiflexibility.

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عنوان ژورنال:
  • The European physical journal. E, Soft matter

دوره 34 9  شماره 

صفحات  -

تاریخ انتشار 2011